Zero electron kinetic energy photoelectron spectroscopy of weakly bound In-NH2CH3, In-NH(CH3)2, and In-N(CH3)3 complexes
Identifieur interne : 00FE25 ( Main/Repository ); précédent : 00FE24; suivant : 00FE26Zero electron kinetic energy photoelectron spectroscopy of weakly bound In-NH2CH3, In-NH(CH3)2, and In-N(CH3)3 complexes
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Abstract
Single-photon pulsed field ionization-zero electron kinetic energy photoelectron spectroscopy has been used to study the indium-methylamine complexes. The photoelectron spectra have been assigned using density functional theory and Franck-Condon calculations. The spectral assignments identify the symmetric In+-N stretch mode for In+-NH2CH3 (259 cm-1), In+-NH(CH3)2 (200 cm-1), and In+-N(CH3)3 (158 cm-1); In-N stretch for In-N(CH3)3 (110 cm-1); In+-N-C bend for In+-NH2CH3 (110 cm-1) and In+-NH(CH3)2 (120 cm-1); In-N-C bend for In-NH2CH3 (91 cm-1) and In-NH(CH3)2 (106 cm-1); and In+-N-H bend for In+-NH(CH3)2 (324 cm-1). Methyl substitutions for hydrogen atoms greatly influence the indium-nitrogen stretch forces and ionization potentials of the complexes. The indium-amine binding in these complexes includes orbital interaction and electrostatic forces. © 2001 American Institute of Physics.
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Zero electron kinetic energy photoelectron spectroscopy of weakly bound In-NH<sub>2</sub>CH<sub>3</sub>, In-NH(CH<sub>3</sub>)<sub>2</sub>, and In-N(CH<sub>3</sub>)<sub>3</sub> complexes</title><author><name sortKey="Rothschopf, Gretchen K" uniqKey="Rothschopf G">Gretchen K. Rothschopf</name><affiliation wicri:level="2"><inist:fA14 i1="01"><s1>Department of Chemistry, University of Kentucky, Lexington, Kentucky 40506-0055</s1><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ></inist:fA14><country xml:lang="fr">États-Unis</country><placeName><region type="state">Kentucky</region></placeName><wicri:cityArea>Department of Chemistry, University of Kentucky, Lexington</wicri:cityArea></affiliation></author><author><name sortKey="Li, Shenggang" uniqKey="Li S">Shenggang Li</name><affiliation wicri:level="2"><inist:fA14 i1="01"><s1>Department of Chemistry, University of Kentucky, Lexington, Kentucky 40506-0055</s1><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ></inist:fA14><country xml:lang="fr">États-Unis</country><placeName><region type="state">Kentucky</region></placeName><wicri:cityArea>Department of Chemistry, University of Kentucky, Lexington</wicri:cityArea></affiliation></author><author><name sortKey="Shannon Perkins, Jimmye" uniqKey="Shannon Perkins J">Jimmye Shannon Perkins</name><affiliation wicri:level="2"><inist:fA14 i1="01"><s1>Department of Chemistry, University of Kentucky, Lexington, Kentucky 40506-0055</s1><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ></inist:fA14><country xml:lang="fr">États-Unis</country><placeName><region type="state">Kentucky</region></placeName><wicri:cityArea>Department of Chemistry, University of Kentucky, Lexington</wicri:cityArea></affiliation></author><author><name sortKey="Yang, Dong Sheng" uniqKey="Yang D">Dong-Sheng Yang</name><affiliation wicri:level="2"><inist:fA14 i1="01"><s1>Department of Chemistry, University of Kentucky, Lexington, Kentucky 40506-0055</s1><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ></inist:fA14><country xml:lang="fr">États-Unis</country><placeName><region type="state">Kentucky</region></placeName><wicri:cityArea>Department of Chemistry, University of Kentucky, Lexington</wicri:cityArea></affiliation></author></titleStmt><publicationStmt><idno type="inist">01-0346077</idno><date when="2001-09-08">2001-09-08</date><idno type="stanalyst">PASCAL 01-0346077 AIP</idno><idno type="RBID">Pascal:01-0346077</idno><idno type="wicri:Area/Main/Corpus">010B41</idno><idno type="wicri:Area/Main/Repository">00FE25</idno></publicationStmt><seriesStmt><idno type="ISSN">0021-9606</idno><title level="j" type="abbreviated">J. chem. phys.</title><title level="j" type="main">The Journal of chemical physics</title></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Density functional method</term><term>Experimental study</term><term>Field ionization</term><term>Franck-Condon factors</term><term>Indium compounds</term><term>Ionization potential</term><term>Organic compounds</term><term>Time of flight mass spectra</term><term>Ultraviolet photoelectron spectra</term><term>Vibrational states</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>3360C</term><term>3115E</term><term>3315R</term><term>3370C</term><term>3320T</term><term>3315M</term><term>3315T</term><term>Etude expérimentale</term><term>Méthode fonctionnelle densité</term><term>Potentiel ionisation</term><term>Facteur Franck Condon</term><term>Etat vibrationnel</term><term>Indium composé</term><term>Composé organique</term><term>Ionisation champ</term><term>Spectre masse temps vol</term><term>Spectre photoélectron UV</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Single-photon pulsed field ionization-zero electron kinetic energy photoelectron spectroscopy has been used to study the indium-methylamine complexes. The photoelectron spectra have been assigned using density functional theory and Franck-Condon calculations. The spectral assignments identify the symmetric In<sup>+</sup>-N stretch mode for In<sup>+</sup>-NH<sub>2</sub>CH<sub>3</sub> (259 cm-1), In<sup>+</sup>-NH(CH<sub>3</sub>)<sub>2</sub> (200 cm-1), and In<sup>+</sup>-N(CH<sub>3</sub>)<sub>3</sub> (158 cm-1); In-N stretch for In-N(CH<sub>3</sub>)<sub>3</sub> (110 cm-1); In<sup>+</sup>-N-C bend for In<sup>+</sup>-NH<sub>2</sub>CH<sub>3</sub> (110 cm-1) and In<sup>+</sup>-NH(CH<sub>3</sub>)<sub>2</sub> (120 cm-1); In-N-C bend for In-NH<sub>2</sub>CH<sub>3</sub> (91 cm-1) and In-NH(CH<sub>3</sub>)<sub>2</sub> (106 cm-1); and In<sup>+</sup>-N-H bend for In<sup>+</sup>-NH(CH<sub>3</sub>)<sub>2</sub> (324 cm-1). Methyl substitutions for hydrogen atoms greatly influence the indium-nitrogen stretch forces and ionization potentials of the complexes. The indium-amine binding in these complexes includes orbital interaction and electrostatic forces. © 2001 American Institute of Physics.</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0021-9606</s0></fA01><fA02 i1="01"><s0>JCPSA6</s0></fA02><fA03 i2="1"><s0>J. chem. phys.</s0></fA03><fA05><s2>115</s2></fA05><fA06><s2>10</s2></fA06><fA08 i1="01" i2="1" l="ENG"><s1>Zero electron kinetic energy photoelectron spectroscopy of weakly bound In-NH<sub>2</sub>CH<sub>3</sub>, In-NH(CH<sub>3</sub>)<sub>2</sub>, and In-N(CH<sub>3</sub>)<sub>3</sub> complexes</s1></fA08><fA11 i1="01" i2="1"><s1>ROTHSCHOPF (Gretchen K.)</s1></fA11><fA11 i1="02" i2="1"><s1>LI (Shenggang)</s1></fA11><fA11 i1="03" i2="1"><s1>SHANNON PERKINS (Jimmye)</s1></fA11><fA11 i1="04" i2="1"><s1>YANG (Dong-Sheng)</s1></fA11><fA14 i1="01"><s1>Department of Chemistry, University of Kentucky, Lexington, Kentucky 40506-0055</s1><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ></fA14><fA20><s1>4565-4572</s1></fA20><fA21><s1>2001-09-08</s1></fA21><fA23 i1="01"><s0>ENG</s0></fA23><fA43 i1="01"><s1>INIST</s1><s2>127</s2></fA43><fA44><s0>8100</s0><s1>© 2001 American Institute of Physics. All rights reserved.</s1></fA44><fA47 i1="01" i2="1"><s0>01-0346077</s0></fA47><fA60><s1>P</s1></fA60><fA61><s0>A</s0></fA61><fA64 i1="01" i2="1"><s0>The Journal of chemical physics</s0></fA64><fA66 i1="01"><s0>USA</s0></fA66><fC01 i1="01" l="ENG"><s0>Single-photon pulsed field ionization-zero electron kinetic energy photoelectron spectroscopy has been used to study the indium-methylamine complexes. The photoelectron spectra have been assigned using density functional theory and Franck-Condon calculations. The spectral assignments identify the symmetric In<sup>+</sup>-N stretch mode for In<sup>+</sup>-NH<sub>2</sub>CH<sub>3</sub> (259 cm-1), In<sup>+</sup>-NH(CH<sub>3</sub>)<sub>2</sub> (200 cm-1), and In<sup>+</sup>-N(CH<sub>3</sub>)<sub>3</sub> (158 cm-1); In-N stretch for In-N(CH<sub>3</sub>)<sub>3</sub> (110 cm-1); In<sup>+</sup>-N-C bend for In<sup>+</sup>-NH<sub>2</sub>CH<sub>3</sub> (110 cm-1) and In<sup>+</sup>-NH(CH<sub>3</sub>)<sub>2</sub> (120 cm-1); In-N-C bend for In-NH<sub>2</sub>CH<sub>3</sub> (91 cm-1) and In-NH(CH<sub>3</sub>)<sub>2</sub> (106 cm-1); and In<sup>+</sup>-N-H bend for In<sup>+</sup>-NH(CH<sub>3</sub>)<sub>2</sub> (324 cm-1). Methyl substitutions for hydrogen atoms greatly influence the indium-nitrogen stretch forces and ionization potentials of the complexes. The indium-amine binding in these complexes includes orbital interaction and electrostatic forces. © 2001 American Institute of Physics.</s0></fC01><fC02 i1="01" i2="3"><s0>001B30C60C</s0></fC02><fC02 i1="02" i2="3"><s0>001B30A15E</s0></fC02><fC02 i1="03" i2="3"><s0>001B30C15R</s0></fC02><fC02 i1="04" i2="3"><s0>001B30C70C</s0></fC02><fC02 i1="05" i2="3"><s0>001B30C20T</s0></fC02><fC02 i1="06" i2="3"><s0>001B30C15M</s0></fC02><fC02 i1="07" i2="3"><s0>001B30C15T</s0></fC02><fC03 i1="01" i2="3" l="FRE"><s0>3360C</s0><s2>PAC</s2><s4>INC</s4></fC03><fC03 i1="02" i2="3" l="FRE"><s0>3115E</s0><s2>PAC</s2><s4>INC</s4></fC03><fC03 i1="03" i2="3" l="FRE"><s0>3315R</s0><s2>PAC</s2><s4>INC</s4></fC03><fC03 i1="04" i2="3" l="FRE"><s0>3370C</s0><s2>PAC</s2><s4>INC</s4></fC03><fC03 i1="05" i2="3" l="FRE"><s0>3320T</s0><s2>PAC</s2><s4>INC</s4></fC03><fC03 i1="06" i2="3" l="FRE"><s0>3315M</s0><s2>PAC</s2><s4>INC</s4></fC03><fC03 i1="07" i2="3" l="FRE"><s0>3315T</s0><s2>PAC</s2><s4>INC</s4></fC03><fC03 i1="08" i2="3" l="FRE"><s0>Etude expérimentale</s0></fC03><fC03 i1="08" i2="3" l="ENG"><s0>Experimental study</s0></fC03><fC03 i1="09" i2="3" l="FRE"><s0>Méthode fonctionnelle densité</s0></fC03><fC03 i1="09" i2="3" l="ENG"><s0>Density functional method</s0></fC03><fC03 i1="10" i2="3" l="FRE"><s0>Potentiel ionisation</s0></fC03><fC03 i1="10" i2="3" l="ENG"><s0>Ionization potential</s0></fC03><fC03 i1="11" i2="3" l="FRE"><s0>Facteur Franck Condon</s0></fC03><fC03 i1="11" i2="3" l="ENG"><s0>Franck-Condon factors</s0></fC03><fC03 i1="12" i2="3" l="FRE"><s0>Etat vibrationnel</s0></fC03><fC03 i1="12" i2="3" l="ENG"><s0>Vibrational states</s0></fC03><fC03 i1="13" i2="3" l="FRE"><s0>Indium composé</s0></fC03><fC03 i1="13" i2="3" l="ENG"><s0>Indium compounds</s0></fC03><fC03 i1="14" i2="3" l="FRE"><s0>Composé organique</s0></fC03><fC03 i1="14" i2="3" l="ENG"><s0>Organic compounds</s0></fC03><fC03 i1="15" i2="3" l="FRE"><s0>Ionisation champ</s0></fC03><fC03 i1="15" i2="3" l="ENG"><s0>Field ionization</s0></fC03><fC03 i1="16" i2="3" l="FRE"><s0>Spectre masse temps vol</s0></fC03><fC03 i1="16" i2="3" l="ENG"><s0>Time of flight mass spectra</s0></fC03><fC03 i1="17" i2="3" l="FRE"><s0>Spectre photoélectron UV</s0></fC03><fC03 i1="17" i2="3" l="ENG"><s0>Ultraviolet photoelectron spectra</s0></fC03><fN21><s1>246</s1></fN21><fN47 i1="01" i2="1"><s0>0135M000403</s0></fN47></pA></standard></inist></record>Pour manipuler ce document sous Unix (Dilib)
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